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Chiral spirosiladiphosphines: ligand development and applications in Rh-catalyzed asymmetric hydrosilylation/cyclization of 1,6-enynes with enhanced reactivity
Spirodiphosphines have been successfully applied in various asymmetric catalytic transformations. However, controlling the coordinating conformations by the direct displacement of the spiro atom remains elusive. Herein, we report the application of Si-centered spirodiphosphine (Si-SDP) ligands in th...
Autores principales: | Hou, Fei, Liu, Minjie, Ru, Tong, Tan, Zequn, Ning, Yingtang, Chen, Fen-Er |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155919/ https://www.ncbi.nlm.nih.gov/pubmed/37152270 http://dx.doi.org/10.1039/d2sc06349b |
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