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Putting cyaphide in its place: determining the donor/acceptor properties of the κC-cyaphido ligand
The synthesis of group 9 pyridine–diimine complexes M((Dipp)PDI)X and [M((Dipp)PDI)L](+) (M = Co, Rh; (Dipp)PDI = 1,1′-(pyridine-2,6-diyl)bis(N-(2,6-diisopropylphenyl)ethan-1-imine); X = CP(−), CCH(−); L = CO, (t)BuNC) bearing a series of strong-field ligands, including the cyaphide ion (C[triple bo...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155923/ https://www.ncbi.nlm.nih.gov/pubmed/37152258 http://dx.doi.org/10.1039/d3sc01126g |