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Exploring Au(i) involving halogen bonding with N-heterocyclic carbene Au(i) aryl complexes in crystalline media

Among the known types of non-covalent interactions with a Au(i) metal center, Au(i) involving halogen bonding (XB) remains a rare phenomenon that has not been studied systematically. Herein, using five N-heterocyclic carbene (NHC) Au(i) aryl complexes and two iodoperfluoroarenes as XB donors, we dem...

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Detalles Bibliográficos
Autores principales: Mikherdov, Alexander S., Jin, Mingoo, Ito, Hajime
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10155931/
https://www.ncbi.nlm.nih.gov/pubmed/37152261
http://dx.doi.org/10.1039/d3sc00373f