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Control of dynamic sp(3)-C stereochemistry

Stereogenic sp(3)-hybridized carbon centres are fundamental building blocks of chiral molecules. Unlike dynamic stereogenic motifs, such as sp(3)-nitrogen centres or atropisomeric biaryls, sp(3)-carbon centres are usually fixed, requiring intermolecular reactions to undergo configurational changes....

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Detalles Bibliográficos
Autores principales: Bismillah, Aisha N., Johnson, Toby G., Hussein, Burhan A., Turley, Andrew T., Saha, Promeet K., Wong, Ho Chi, Aguilar, Juan A., Yufit, Dmitry S., McGonigal, Paul R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10159849/
https://www.ncbi.nlm.nih.gov/pubmed/36914791
http://dx.doi.org/10.1038/s41557-023-01156-7