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Control of dynamic sp(3)-C stereochemistry
Stereogenic sp(3)-hybridized carbon centres are fundamental building blocks of chiral molecules. Unlike dynamic stereogenic motifs, such as sp(3)-nitrogen centres or atropisomeric biaryls, sp(3)-carbon centres are usually fixed, requiring intermolecular reactions to undergo configurational changes....
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10159849/ https://www.ncbi.nlm.nih.gov/pubmed/36914791 http://dx.doi.org/10.1038/s41557-023-01156-7 |