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Synthesis, crystal structure and thermal decomposition pathway of bis(isoselenocyanato-κN)tetrakis(pyridine-κN)manganese(II)
The reaction of MnCl(2)·2H(2)O with KSeCN and pyridine in water leads to the formation of the title complex, [Mn(NCSe)(2)(C(5)H(5)N)(4)], which is isotypic to its Fe, Co, Ni, Zn and Cd analogues. In its crystal structure, discrete complexes are observed that are located on centres of inversion. The...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10162072/ https://www.ncbi.nlm.nih.gov/pubmed/37151823 http://dx.doi.org/10.1107/S2056989023003535 |