Characterization and Fate of a Septanosyl Ferrier Cation in the Gas and Solution Phases

[Image: see text] Ferrier reactions follow a mechanistic pathway whereby Lewis acid activation of a cyclic enol ether facilitates departure of an allylic leaving group to form a glycosyl Ferrier cation. Attack on the Ferrier cation provides a new acetal linkage concurrent with the transposition of t...

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Detalles Bibliográficos
Autores principales: Greis, Kim, Griesbach, Caleb E., Kirschbaum, Carla, Meijer, Gerard, von Helden, Gert, Pagel, Kevin, Peczuh, Mark W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10167658/
https://www.ncbi.nlm.nih.gov/pubmed/37092271
http://dx.doi.org/10.1021/acs.joc.3c00079

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10167658/
https://www.ncbi.nlm.nih.gov/pubmed/37092271
http://dx.doi.org/10.1021/acs.joc.3c00079

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