Cargando…
Characterization and Fate of a Septanosyl Ferrier Cation in the Gas and Solution Phases
[Image: see text] Ferrier reactions follow a mechanistic pathway whereby Lewis acid activation of a cyclic enol ether facilitates departure of an allylic leaving group to form a glycosyl Ferrier cation. Attack on the Ferrier cation provides a new acetal linkage concurrent with the transposition of t...
| Autores principales: | , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10167658/ https://www.ncbi.nlm.nih.gov/pubmed/37092271 http://dx.doi.org/10.1021/acs.joc.3c00079 |