Tandem addition of nucleophilic and electrophilic reagents to vinyl phosphinates: the stereoselective formation of organophosphorus compounds with congested tertiary carbons

Carbon anions formed via the addition of Grignard reagents to S(P)-vinyl phosphinates were modified with electrophilic reagents to afford organophosphorus compounds with diverse carbon skeletons. The electrophiles included acids, aldehydes, epoxy groups, chalcogens and alkyl halides. When alkyl hali...

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Detalles Bibliográficos
Autores principales: Lin, Zhu, Zhai, De-Hua, Sun, Yong-Ming, Zheng, Hong-Xing, Li, Qiang, Wang, Yan-Lan, Wen, Jing-Hong, Zhao, Chang-Qiu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10167796/
https://www.ncbi.nlm.nih.gov/pubmed/37179997
http://dx.doi.org/10.1039/d3ra02409a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10167796/
https://www.ncbi.nlm.nih.gov/pubmed/37179997
http://dx.doi.org/10.1039/d3ra02409a

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