Cargando…
On the existence of low-valent magnesium–calcium complexes
DFT-Calculations predict that a low-valent complex (BDI)Mg–Ca(BDI) with bulky β-diketiminate (BDI) ligands is thermodynamically stable. It was attempted to isolate such a complex by salt-metathesis between [((DIPeP)BDI*)Mg(−)Na(+)](2) and [((DIPeP)BDI)CaI](2) ((DIPeP)BDI = HC[C(Me)N-DIPeP](2); (DIPe...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10171184/ https://www.ncbi.nlm.nih.gov/pubmed/37181774 http://dx.doi.org/10.1039/d3sc00909b |