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On the existence of low-valent magnesium–calcium complexes

DFT-Calculations predict that a low-valent complex (BDI)Mg–Ca(BDI) with bulky β-diketiminate (BDI) ligands is thermodynamically stable. It was attempted to isolate such a complex by salt-metathesis between [((DIPeP)BDI*)Mg(−)Na(+)](2) and [((DIPeP)BDI)CaI](2) ((DIPeP)BDI = HC[C(Me)N-DIPeP](2); (DIPe...

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Detalles Bibliográficos
Autores principales:	Mai, Jonathan, Rösch, Bastian, Patel, Neha, Langer, Jens, Harder, Sjoerd
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10171184/ https://www.ncbi.nlm.nih.gov/pubmed/37181774 http://dx.doi.org/10.1039/d3sc00909b

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