Tantalum ureate complexes for photocatalytic hydroaminoalkylation

Using a tantalum ureate pre-catalyst, photocatalytic hydroaminoalkylation of unactivated alkenes with unprotected amines at room temperature is demonstrated. The combination of Ta(CH(2)SiMe(3))(3)Cl(2) and a ureate ligand with a saturated cyclic backbone resulted in this unique reactivity. Prelimina...

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Detalles Bibliográficos
Autores principales: Hao, Han, Manßen, Manfred, Schafer, Laurel L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10171191/
https://www.ncbi.nlm.nih.gov/pubmed/37181785
http://dx.doi.org/10.1039/d3sc00042g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10171191/
https://www.ncbi.nlm.nih.gov/pubmed/37181785
http://dx.doi.org/10.1039/d3sc00042g

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