Snapshots of sequential polyphosphide rearrangement upon metallatetrylene addition

Insertion and functionalization of gallasilylenes [L(Ph)Si–Ga(Cl)L(BDI)] (L(Ph) = PhC(NtBu)(2); L(BDI) = [{2,6-iPr(2)C(6)H(3)NCMe}(2)CH]) into the cyclo-E(5) rings of [Cp*Fe(η(5)-E(5))] (Cp* = η(5)-C(5)Me(5); E = P, As) are reported. Reactions of [Cp*Fe(η(5)-E(5))] with gallasilylene result in E–E/S...

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Detalles Bibliográficos
Autores principales: Sun, Xiaofei, Hinz, Alexander, Schulz, Stephan, Zimmermann, Lisa, Scheer, Manfred, Roesky, Peter W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10171192/
https://www.ncbi.nlm.nih.gov/pubmed/37181779
http://dx.doi.org/10.1039/d3sc00806a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10171192/
https://www.ncbi.nlm.nih.gov/pubmed/37181779
http://dx.doi.org/10.1039/d3sc00806a

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