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Snapshots of sequential polyphosphide rearrangement upon metallatetrylene addition
Insertion and functionalization of gallasilylenes [L(Ph)Si–Ga(Cl)L(BDI)] (L(Ph) = PhC(NtBu)(2); L(BDI) = [{2,6-iPr(2)C(6)H(3)NCMe}(2)CH]) into the cyclo-E(5) rings of [Cp*Fe(η(5)-E(5))] (Cp* = η(5)-C(5)Me(5); E = P, As) are reported. Reactions of [Cp*Fe(η(5)-E(5))] with gallasilylene result in E–E/S...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10171192/ https://www.ncbi.nlm.nih.gov/pubmed/37181779 http://dx.doi.org/10.1039/d3sc00806a |