Three-Component Approach to Densely Functionalized Trifluoromethyl Allenols by Asymmetric Organocatalysis

[Image: see text] We have developed a new three-component catalytic coupling reaction of alkynyl boronates, diazomethanes, and aliphatic/aromatic ketones in the presence of BINOL derivatives. The reaction proceeds with a remarkably high enantio- and diastereoselectivity (up to three contiguous stere...

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Detalles Bibliográficos
Autores principales: Deliaval, Marie, Jayarajan, Ramasamy, Eriksson, Lars, Szabó, Kálmán J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10176480/
https://www.ncbi.nlm.nih.gov/pubmed/37126044
http://dx.doi.org/10.1021/jacs.3c02852

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10176480/
https://www.ncbi.nlm.nih.gov/pubmed/37126044
http://dx.doi.org/10.1021/jacs.3c02852

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