Nickel Meets Aryl Thianthrenium Salts: Ni(I)-Catalyzed Halogenation of Arenes

[Image: see text] Herein, a regioselective, late-stage two-step arene halogenation method is reported. We propose how unusual Ni(I)/(III) catalysis is enabled by a combination of aryl thianthrenium and Ni redox properties that is hitherto unachieved with other (pseudo)halides. The catalyst is access...

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Detalles Bibliográficos
Autores principales: Ni, Shengyang, Yan, Jiyao, Tewari, Srija, Reijerse, Edward J., Ritter, Tobias, Cornella, Josep
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10176483/
https://www.ncbi.nlm.nih.gov/pubmed/37126771
http://dx.doi.org/10.1021/jacs.3c02611

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10176483/
https://www.ncbi.nlm.nih.gov/pubmed/37126771
http://dx.doi.org/10.1021/jacs.3c02611

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