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New Chemistry of Chiral 1,3-Dioxolan-4-Ones

(2S,5S)-5-Phenyl-2-t-butyl-1,3-dioxolan-4-one, readily derived from mandelic acid, undergoes the Michael addition to butenolide and 4-methoxy-β-nitrostyrene with the absolute configuration of the products confirmed by X-ray diffraction in each case. In the former case, thermal fragmentation gives th...

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Detalles Bibliográficos
Autores principales: Aitken, R. Alan, Power, Lynn A., Slawin, Alexandra M. Z.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10180285/
https://www.ncbi.nlm.nih.gov/pubmed/37175260
http://dx.doi.org/10.3390/molecules28093845