Cargando…

A step-for-step main-group replica of the Fischer carbene synthesis at a borylene carbonyl

The Fischer carbene synthesis, involving the conversion of a transition metal (TM)-bound CO ligand to a carbene ligand of the form [=C(OR’)R] (R, R’ = organyl groups), is one of the seminal reactions in the history of organometallic chemistry. Carbonyl complexes of p-block elements, of the form [E(C...

Descripción completa

Detalles Bibliográficos
Autores principales: Härterich, Marcel, Matler, Alexander, Dewhurst, Rian D., Sachs, Andreas, Oppel, Kai, Stoy, Andreas, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10183005/
https://www.ncbi.nlm.nih.gov/pubmed/37179413
http://dx.doi.org/10.1038/s41467-023-36251-3