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Transition-Metal Isocorroles as Singlet Oxygen Sensitizers

[Image: see text] Building on a highly efficient synthesis of pyrrole-appended isocorroles, we have worked out conditions for manganese, palladium, and platinum insertion into free-base 5/10-(2-pyrrolyl)-5,10,15-tris(4-methylphenyl)isocorrole, H(2)[5/10-(2-py)TpMePiC]. Platinum insertion proved exce...

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Detalles Bibliográficos
Autores principales: Larsen, Simon, Adewuyi, Joseph A., Ung, Gaël, Ghosh, Abhik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10189730/
https://www.ncbi.nlm.nih.gov/pubmed/37141580
http://dx.doi.org/10.1021/acs.inorgchem.3c00782