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Regiodivergent (3 + 2) annulation reactions of oxyallyl cations

We report a new method for the regiodivergent dearomative (3 + 2) reaction between 3-substituted indoles and oxyallyl cations. Access to both regioisomeric products is possible and is contingent on the presence or absence of a bromine atom on the substituted oxyallyl cation. In this way, we are able...

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Detalles Bibliográficos
Autores principales: Protich, Zachary, Lowder, Leah L., Hughes, Russell P., Wu, Jimmy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10189855/
https://www.ncbi.nlm.nih.gov/pubmed/37206390
http://dx.doi.org/10.1039/d2sc06999g