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Bicyclic (alkyl)(amino)carbene (BICAAC) in a dual role: activation of primary amides and CO(2) towards catalytic N-methylation
Herein, we report the first catalytic methylation of primary amides using CO(2) as a C1 source. A bicyclic (alkyl)(amino)carbene (BICAAC) exhibits dual role by activating both primary amide and CO(2) to carry out this catalytic transformation which enables the formation of a new C–N bond in the pres...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10189868/ https://www.ncbi.nlm.nih.gov/pubmed/37206403 http://dx.doi.org/10.1039/d3sc01216f |