Bicyclic (alkyl)(amino)carbene (BICAAC) in a dual role: activation of primary amides and CO(2) towards catalytic N-methylation

Herein, we report the first catalytic methylation of primary amides using CO(2) as a C1 source. A bicyclic (alkyl)(amino)carbene (BICAAC) exhibits dual role by activating both primary amide and CO(2) to carry out this catalytic transformation which enables the formation of a new C–N bond in the pres...

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Detalles Bibliográficos
Autores principales: Gautam, Nimisha, Logdi, Ratan, P., Sreejyothi, Roy, Antara, Tiwari, Ashwani K., Mandal, Swadhin K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10189868/
https://www.ncbi.nlm.nih.gov/pubmed/37206403
http://dx.doi.org/10.1039/d3sc01216f

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