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ItOct (ItOctyl) – pushing the limits of ItBu: highly hindered electron-rich N-aliphatic N-heterocyclic carbenes

ItBu (ItBu = 1,3-di-tert-butylimidazol-2-ylidene) represents the most important and most versatile N-alkyl N-heterocyclic carbene available in organic synthesis and catalysis. Herein, we report the synthesis, structural characterization and catalytic activity of ItOct (ItOctyl), C(2)-symmetric, high...

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Detalles Bibliográficos
Autores principales: Rahman, Md. Mahbubur, Meng, Guangrong, Bisz, Elwira, Dziuk, Błażej, Lalancette, Roger, Szostak, Roman, Szostak, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10189875/
https://www.ncbi.nlm.nih.gov/pubmed/37206400
http://dx.doi.org/10.1039/d3sc01006f