Cargando…

ItOct (ItOctyl) – pushing the limits of ItBu: highly hindered electron-rich N-aliphatic N-heterocyclic carbenes

ItBu (ItBu = 1,3-di-tert-butylimidazol-2-ylidene) represents the most important and most versatile N-alkyl N-heterocyclic carbene available in organic synthesis and catalysis. Herein, we report the synthesis, structural characterization and catalytic activity of ItOct (ItOctyl), C(2)-symmetric, high...

Descripción completa

Detalles Bibliográficos
Autores principales:	Rahman, Md. Mahbubur, Meng, Guangrong, Bisz, Elwira, Dziuk, Błażej, Lalancette, Roger, Szostak, Roman, Szostak, Michal
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10189875/ https://www.ncbi.nlm.nih.gov/pubmed/37206400 http://dx.doi.org/10.1039/d3sc01006f

Ejemplares similares

IPr# – highly hindered, broadly applicable N-heterocyclic carbenes
por: Zhao, Qun, et al.
Publicado: (2021)

[IPr(#)–PEPPSI]: A Well-Defined, Highly Hindered and Broadly Applicable Pd(II)–NHC (NHC = N-Heterocyclic Carbene) Precatalyst for Cross-Coupling Reactions
por: Rahman, Md. Mahbubur, et al.
Publicado: (2023)

Iron-Catalyzed C(sp(2))–C(sp(3)) Cross-Coupling of Aryl Chlorobenzoates with Alkyl Grignard Reagents
por: Bisz, Elwira, et al.
Publicado: (2020)

Sequential Iron-Catalyzed C(sp(2))–C(sp(3)) Cross-Coupling of Chlorobenzamides/Chemoselective Amide Reduction and Reductive Deuteration to Benzylic Alcohols
por: Bisz, Elwira, et al.
Publicado: (2022)

Suzuki–Miyaura cross-coupling of amides and esters at room temperature: correlation with barriers to rotation around C–N and C–O bonds
por: Lei, Peng, et al.
Publicado: (2017)

Transamidation of Amides and Amidation of Esters by Selective N–C(O)/O–C(O) Cleavage Mediated by Air- and Moisture-Stable Half-Sandwich Nickel(II)–NHC Complexes
por: Buchspies, Jonathan, et al.
Publicado: (2021)

Iron-Catalyzed Cross-Coupling Reactions of Alkyl Grignards with Aryl Chlorobenzenesulfonates
por: Bisz, Elwira
Publicado: (2021)

Novel stereoselective syntheses of N-octyl-β-valienamine (NOV) and N-octyl-4-epi-β-valienamine (NOEV) from (−)-shikimic acid
por: Li, Feng-Lei, et al.
Publicado: (2019)

Thiazol-2-ylidenes as N-Heterocyclic carbene ligands with enhanced electrophilicity for transition metal catalysis
por: Zhang, Jin, et al.
Publicado: (2022)

Highly chemoselective ruthenium(ii)-catalyzed direct arylation of cyclic and N,N-dialkyl benzamides with aryl silanes
por: Nareddy, Pradeep, et al.
Publicado: (2017)

Metal-free tandem carbene N–H insertions and C–C bond cleavages
por: Chen, Pu, et al.
Publicado: (2020)

Cross-Dehydrogenative N–N Coupling of Aromatic and Aliphatic Methoxyamides with Benzotriazoles
por: Vemuri, Pooja Y., et al.
Publicado: (2021)

Synthesis and photophysical studies of an indigo derivative: N-octyl-7,7′-diazaindigo
por: de Miguel, Gustavo, et al.
Publicado: (2020)

Ribosomal Synthesis of N-Methyl Peptides
por: Subtelny, Alexander O., et al.
Publicado: (2008)

Comparison of 2-octyl cyanoacrylate and n-octyl cyanoacrylate topical skin adhesives for wound closure after ankle fracture surgery: a prospective randomized trial
por: Park, Young Hwan, et al.
Publicado: (2023)

Nonuniform STM Contrast of Self-Assembled Tri-n-octyl-triazatriangulenium Tetrafluoroborate on HOPG
por: Snegir, Sergii, et al.
Publicado: (2023)

Degradable copolymer based on amphiphilic N-octyl-N-quatenary chitosan and low-molecular weight polyethylenimine for gene delivery
por: Liu, Chengchu, et al.
Publicado: (2012)

Synthesis of Well-Defined Poly(N-H Benzamide-co-N-Octyl Benzamide)s and the Study of their Blends with Nylon 6
por: Huang, Chih-Feng, et al.
Publicado: (2017)

Green Synthesis and Bioactivity of Aliphatic N-Substituted Glycine Derivatives
por: Jafari, Ameneh, et al.
Publicado: (2023)

Electron and hydrogen self-exchange of free radicals of sterically hindered tertiary aliphatic amines investigated by photo-CIDNP
por: Goez, Martin, et al.
Publicado: (2013)

Phosphonic Acid Analogs of Fluorophenylalanines as Inhibitors of Human and Porcine Aminopeptidases N: Validation of the Importance of the Substitution of the Aromatic Ring
por: Wanat, Weronika, et al.
Publicado: (2020)

5-Nitro-1-n-octyl-1H-benzimidazol-2(3H)-one
por: Ouzidan, Younes, et al.
Publicado: (2011)

Safety assessment of the substance poly(2‐hydroxypropanoic acid), n‐octyl/n‐decyl esters, for use in food contact materials
por: Lambré, Claude, et al.
Publicado: (2023)

Nanoparticles Prepared From N,N-Dimethyl-N-Octyl Chitosan as the Novel Approach for Oral Delivery of Insulin: Preparation, Statistical Optimization and In-vitro Characterization
por: Shamsa, Elnaz Sadat, et al.
Publicado: (2018)

Pd@[nBu(4)][Br] as a Simple Catalytic System for N-Alkylation Reactions with Alcohols
por: Cacciuttolo, Bastien, et al.
Publicado: (2016)

2,4-Di-tert-butyl-6-({[2-(dimethylamino)ethyl](2-hydroxybenzyl)amino}methyl)phenol
por: Spaleniak, Grzegorz P., et al.
Publicado: (2014)

Sterically Tuned N-Heterocyclic Carbene Ligands for the Efficient Formation of Hindered Products in Ru-Catalyzed Olefin Metathesis
por: Planer, Sebastian, et al.
Publicado: (2020)

Low-temperature superstructure of [(N,N-diisobutylcarbamoyl)methyl]octyl(phenyl)phosphine oxide (CMPO)
por: Pojarová, Michaela, et al.
Publicado: (2011)

Pattern recognition analysis of a set of mutagenic aliphatic N-nitrosamines.
por: Nesnow, S, et al.
Publicado: (1985)

Photocatalytic Decarboxylative Coupling of Aliphatic N‐hydroxyphthalimide Esters with Polyfluoroaryl Nucleophiles
por: Yi, Xiangli, et al.
Publicado: (2021)

N-(3-Octyl-4-oxo-1,3-thiazolidin-2-ylidene)benzamide
por: Zhao, Hua-Rong, et al.
Publicado: (2010)

N2′→P3′ Phosphoramidate Glycerol Nucleic Acid as a Potential Alternative Genetic System
por: Chen, Jesse J., et al.
Publicado: (2009)

CeCl(3)/n‐BuLi: Unraveling Imamoto's Organocerium Reagent
por: Berger, Tassilo, et al.
Publicado: (2021)

Functionalization of N-arylglycine esters: electrocatalytic access to C–C bonds mediated by n-Bu(4)NI
por: Luo, Mi-Hai, et al.
Publicado: (2018)

Uncovering the Importance of Proton Donors in TmI(2)-Promoted Electron Transfer: Facile C−N Bond Cleavage in Unactivated Amides**
por: Szostak, Michal, et al.
Publicado: (2013)

Crystal structure of a palladium(II) complex containing the wide bite-angle bis(selenium) ligand, cis-[((t)BuNH)(Se)P(μ-N(t)Bu)(2)P(Se)(NH(t)Bu)]
por: Bonnette, Austin, et al.
Publicado: (2018)

Self-Assembly, Surface Activity and Structure of n-Octyl-β-D-thioglucopyranoside in Ethylene Glycol-Water Mixtures
por: Ruiz, Cristóbal Carnero, et al.
Publicado: (2013)

Itaconic Acid Based Surfactants: I. Synthesis and Characterization of Sodium n-Octyl Sulfoitaconate Diester Anionic Surfactant
por: Xu, Jun, et al.
Publicado: (2016)

Unexpected Acetylation of Endogenous Aliphatic Amines by Arylamine N‐Acetyltransferase NAT2
por: Conway, Louis P., et al.
Publicado: (2020)

Direct Preparation of N-Substituted Pyrazoles from Primary Aliphatic or Aromatic Amines
por: Gulia, Nurbey, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_io124c0vi02k4lg0rjkh754o6c