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A cheap metal catalyzed ring expansion/cross-coupling cascade: a new route to functionalized medium-sized and macrolactones

An efficient alkoxyl radical-triggered ring expansion/cross-coupling cascade was developed under cheap metal catalysis. Through the metal-catalyzed radical relay strategy, a wide range of medium-sized lactones (9–11 membered) and macrolactones (12, 13, 15, 18, and 19-membered) were constructed in mo...

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Detalles Bibliográficos
Autores principales: Liu, Shuai, Ma, Pengchen, Zhang, Lu, Shen, Shenyu, Miao, Hong-Jie, Liu, Le, Houk, K. N., Duan, Xin-Hua, Guo, Li-Na
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10189895/
https://www.ncbi.nlm.nih.gov/pubmed/37206389
http://dx.doi.org/10.1039/d2sc06157k