A donor-supported silavinylidene and silylium ylides: boroles as a flexible platform for versatile Si(ii) chemistry

Electron-deficient, anti-aromatic 2,5-disilyl boroles are shown to be a flexibly adaptive molecular platform with regards to SiMe(3) mobility in their reaction with the nucleophilic donor-stabilised precursor dichloro silylene SiCl(2)(IDipp). Depending on the substitution pattern, selective formatio...

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Detalles Bibliográficos
Autores principales: Sarcevic, Julijan, Heitkemper, Tobias, Ruth, Paul Niklas, Naß, Leonard, Kubis, Maximilian, Stalke, Dietmar, Sindlinger, Christian P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10189903/
https://www.ncbi.nlm.nih.gov/pubmed/37206392
http://dx.doi.org/10.1039/d3sc00808h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10189903/
https://www.ncbi.nlm.nih.gov/pubmed/37206392
http://dx.doi.org/10.1039/d3sc00808h

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