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A donor-supported silavinylidene and silylium ylides: boroles as a flexible platform for versatile Si(ii) chemistry
Electron-deficient, anti-aromatic 2,5-disilyl boroles are shown to be a flexibly adaptive molecular platform with regards to SiMe(3) mobility in their reaction with the nucleophilic donor-stabilised precursor dichloro silylene SiCl(2)(IDipp). Depending on the substitution pattern, selective formatio...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10189903/ https://www.ncbi.nlm.nih.gov/pubmed/37206392 http://dx.doi.org/10.1039/d3sc00808h |