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Molybdenum carbonyl assisted reductive tetramerization of CO by activated magnesium(i) compounds: squarate dianion vs. metallo-ketene formation
Reactions of a dimagnesium(i) compound, [{((Dip)Nacnac)Mg}(2)] ((Dip)Nacnac = [HC(MeCNDip)(2)](−), Dip = 2,6-diisopropylphenyl), pre-activated by coordination with simple Lewis bases (4-dimethylaminopyridine, DMAP; or TMC, :C(MeNCMe)(2)), with 1 atmosphere of CO in the presence of one equivalent of...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10189904/ https://www.ncbi.nlm.nih.gov/pubmed/37206401 http://dx.doi.org/10.1039/d3sc01487h |