Pd-Catalyzed Organometallic-Free Homologation of Arylboronic Acids Enabled by Chemoselective Transmetalation

[Image: see text] A Pd-catalyzed homologation of arylboronic acids is reported. Halomethylboronic acid pinacol esters (Bpin) undergo a remarkably facile, yet rare, oxidative addition enabled by an α-boryl effect. Simultaneous chemoselective transmetalation allows use of these metalloid reagents for...

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Detalles Bibliográficos
Autores principales: Bastick, Kane A. C., Watson, Allan J. B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10204063/
https://www.ncbi.nlm.nih.gov/pubmed/37229436
http://dx.doi.org/10.1021/acscatal.3c00921

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10204063/
https://www.ncbi.nlm.nih.gov/pubmed/37229436
http://dx.doi.org/10.1021/acscatal.3c00921

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