Direct allylic acylation via cross-coupling involving cooperative N‑heterocyclic carbene, hydrogen atom transfer, and photoredox catalysis

Herein, we report a mild, operationally simple, multicatalytic method for the synthesis of β,γ-unsaturated ketones via allylic acylation of alkenes. Specifically, the method combines N‑heterocyclic carbene catalysis, hydrogen atom transfer catalysis, and photoredox catalysis for cross-coupling react...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Xiaochen, Yang, Rongxin, Zhu, Binbing, Liu, Yuxiu, Song, Hongjian, Dong, Jianyang, Wang, Qingmin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10206076/
https://www.ncbi.nlm.nih.gov/pubmed/37221185
http://dx.doi.org/10.1038/s41467-023-38743-8

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10206076/
https://www.ncbi.nlm.nih.gov/pubmed/37221185
http://dx.doi.org/10.1038/s41467-023-38743-8

Ejemplares similares