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Direct allylic acylation via cross-coupling involving cooperative N‑heterocyclic carbene, hydrogen atom transfer, and photoredox catalysis

Herein, we report a mild, operationally simple, multicatalytic method for the synthesis of β,γ-unsaturated ketones via allylic acylation of alkenes. Specifically, the method combines N‑heterocyclic carbene catalysis, hydrogen atom transfer catalysis, and photoredox catalysis for cross-coupling react...

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Detalles Bibliográficos
Autores principales:	Wang, Xiaochen, Yang, Rongxin, Zhu, Binbing, Liu, Yuxiu, Song, Hongjian, Dong, Jianyang, Wang, Qingmin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10206076/ https://www.ncbi.nlm.nih.gov/pubmed/37221185 http://dx.doi.org/10.1038/s41467-023-38743-8

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