Synthesis, bridgehead functionalization, and photoisomerization of 9,10-diboratatriptycene dianions

9,10-Diboratatriptycene salts M(2)[RB(μ-C(6)H(4))(3)BR] (R = H, Me; M(+) = Li(+), K(+), [n-Bu(4)N](+)) have been synthesized via [4 + 2] cycloaddition between doubly reduced 9,10-dihydro-9,10-diboraanthracenes M(2)[DBA] and benzyne, generated in situ from C(6)H(5)F and C(6)H(5)Li or LiN(i-Pr)(2). [H...

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Detalles Bibliográficos
Autores principales: Prey, Sven E., Gilmer, Jannik, Teichmann, Samira V., Čaić, Luis, Wenisch, Mischa, Bolte, Michael, Virovets, Alexander, Lerner, Hans-Wolfram, Fantuzzi, Felipe, Wagner, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10207881/
https://www.ncbi.nlm.nih.gov/pubmed/37234897
http://dx.doi.org/10.1039/d3sc00555k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10207881/
https://www.ncbi.nlm.nih.gov/pubmed/37234897
http://dx.doi.org/10.1039/d3sc00555k

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