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Synthesis, bridgehead functionalization, and photoisomerization of 9,10-diboratatriptycene dianions
9,10-Diboratatriptycene salts M(2)[RB(μ-C(6)H(4))(3)BR] (R = H, Me; M(+) = Li(+), K(+), [n-Bu(4)N](+)) have been synthesized via [4 + 2] cycloaddition between doubly reduced 9,10-dihydro-9,10-diboraanthracenes M(2)[DBA] and benzyne, generated in situ from C(6)H(5)F and C(6)H(5)Li or LiN(i-Pr)(2). [H...
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10207881/ https://www.ncbi.nlm.nih.gov/pubmed/37234897 http://dx.doi.org/10.1039/d3sc00555k |