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A redox-active inorganic crown ether based on a polyoxometalate capsule

Cation-uptake has been long researched as an important topic in materials science. Herein we focus on a molecular crystal composed of a charge-neutral polyoxometalate (POM) capsule [Mo(VI)(72)Fe(III)(30)O(252)(H(2)O)(102)(CH(3)CO(2))(15)](3+) encapsulating a Keggin-type phosphododecamolybdate anion...

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Detalles Bibliográficos
Autores principales: Tamai, Nanako, Ogiwara, Naoki, Hayashi, Eri, Kamata, Keigo, Misawa, Toshiyuki, Ito, Takeru, Kojima, Tatsuhiro, Segado, Mireia, Petrus, Enric, Bo, Carles, Uchida, Sayaka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10208027/
https://www.ncbi.nlm.nih.gov/pubmed/37234904
http://dx.doi.org/10.1039/d3sc01077e