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Ruthenium-catalysed decarboxylative unsymmetric dual ortho-/meta-C–H bond functionalization of arenecarboxylic acids

Here, we describe a ruthenium-catalysed decarboxylative unsymmetric ortho-C–H azaarylation/meta-C–H alkylation via a traceless directing group relay strategy. The installation of a 2-pyridyl functionality via carboxyl directed ortho-C–H activation is critical to promote decarboxylation and enable me...

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Detalles Bibliográficos
Autores principales: Li, Xiankai, Wang, Xiaofei, Zhang, Jing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10208063/
https://www.ncbi.nlm.nih.gov/pubmed/37234909
http://dx.doi.org/10.1039/d3sc01226c