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Concerted Proton-Coupled Electron Transfer to a Graphite Adsorbed Metalloporphyrin Occurs by Band to Bond Electron Redistribution

[Image: see text] Surface immobilized catalysts are highly promising candidates for a range of energy conversion reactions, and atomistic mechanistic understanding is essential for their rational design. Cobalt tetraphenylporphyrin (CoTPP) nonspecifically adsorbed on a graphitic surface has been sho...

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Detalles Bibliográficos
Autores principales: Hutchison, Phillips, Kaminsky, Corey J., Surendranath, Yogesh, Hammes-Schiffer, Sharon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10214502/
https://www.ncbi.nlm.nih.gov/pubmed/37252356
http://dx.doi.org/10.1021/acscentsci.3c00186