α-Vinylation of Ester Equivalents via Main Group Catalysis for the Construction of Quaternary Centers

[Image: see text] A methodology for the construction of sterically congested quaternary centers via the trapping of vinyl carbocations with silyl ketene acetals is disclosed. This main group-catalyzed α-vinylation reaction is advantageous as methods to access these congested motifs are limited. More...

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Detalles Bibliográficos
Autores principales: Williams, Chloe G., Nistanaki, Sepand K., Wells, Conner W., Nelson, Hosea M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10226172/
https://www.ncbi.nlm.nih.gov/pubmed/37192420
http://dx.doi.org/10.1021/acs.orglett.3c00535

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10226172/
https://www.ncbi.nlm.nih.gov/pubmed/37192420
http://dx.doi.org/10.1021/acs.orglett.3c00535

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