The double protonation of dihapto-coordinated benzene complexes enables dearomatization using aromatic nucleophiles

Friedel-Crafts Arylation (the Scholl reaction) is the coupling of two aromatic rings with the aid of a strong Lewis or Brønsted acid. This historically significant C–C bond forming reaction normally leads to aromatic products, often as oligomeric mixtures, dictated by the large stabilization gained...

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Detalles Bibliográficos
Autores principales: Weatherford-Pratt, Justin T., Smith, Jacob A., Bloch, Jeremy M., Ericson, Megan N., Myers, Jeffery T., Westendorff, Karl S., Dickie, Diane A., Dean Harman, W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10229636/
https://www.ncbi.nlm.nih.gov/pubmed/37253764
http://dx.doi.org/10.1038/s41467-023-38945-0

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10229636/
https://www.ncbi.nlm.nih.gov/pubmed/37253764
http://dx.doi.org/10.1038/s41467-023-38945-0

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