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The double protonation of dihapto-coordinated benzene complexes enables dearomatization using aromatic nucleophiles
Friedel-Crafts Arylation (the Scholl reaction) is the coupling of two aromatic rings with the aid of a strong Lewis or Brønsted acid. This historically significant C–C bond forming reaction normally leads to aromatic products, often as oligomeric mixtures, dictated by the large stabilization gained...
Autores principales: | Weatherford-Pratt, Justin T., Smith, Jacob A., Bloch, Jeremy M., Ericson, Megan N., Myers, Jeffery T., Westendorff, Karl S., Dickie, Diane A., Dean Harman, W. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10229636/ https://www.ncbi.nlm.nih.gov/pubmed/37253764 http://dx.doi.org/10.1038/s41467-023-38945-0 |
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