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Atom-economic and stereoselective catalytic synthesis of fully substituted enol esters/carbonates of amides in acyclic systems enabled by boron Lewis acid catalysis

Carboacyloxylation of internal alkynes is emerging as a powerful and straightforward strategy for enol ester synthesis. However, the reported examples come with limitations, including the utilization of noble metal catalysts, the control of regio- and Z/E selectivity, and an application in the synth...

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Detalles Bibliográficos
Autores principales: Xiao, Yuanjiu, Tang, Lei, Xu, Tong-Tong, Sheng, Jiang-Yi-Hui, Zhou, Zhongyan, Yue, Lei, Wang, Guoqiang, Oestreich, Martin, Feng, Jian-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10231430/
https://www.ncbi.nlm.nih.gov/pubmed/37265723
http://dx.doi.org/10.1039/d3sc01394d