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Tetra­kis(tri­ethyl­enediamin-1-ium) dodeca-μ(2)-chlorido-hexakis(thio­cyanato-κN)hexa-octa­hedro-niobate

The crystal structure of the cluster complex salt, (C(6)H(13)N(2))(4)[Nb(6)(NCS)(6)Cl(12)] or (H-DABCO)(4)[Nb(6)Cl(12)(NCS)(6)] (DABCO = tri­ethyl­enedi­amine or 1,4-di­aza­bicyclo­[2.2.2]octa­ne), comprises octa­hedral Nb(6) cluster cores, which are μ(2)-coordinated by 12 chloride ligands (bridging...

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Detalles Bibliográficos
Autores principales: Sperlich, Eric, Köckerling, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10242733/
https://www.ncbi.nlm.nih.gov/pubmed/37287859
http://dx.doi.org/10.1107/S241431462300398X