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Syntheses, crystal structures, Hirshfeld surface analyses and energy frameworks of two 4-amino­anti­pyrine Schiff base compounds: (E)-4-{[4-(di­ethyl­amino)­benzyl­idene]amino}-1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one and (E)-4-[(4-fluoro­benzyl­idene)amino]-1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one

The title Schiff base compounds, C(22)H(26)N(4)O (I) and C(18)H(16)FN(3)O (II), were each synthesized by a single-step condensation reaction. The substituted benzyl­idene ring is inclined to the pyrazole ring mean planes by 22.92 (7)° in I and 12.70 (9)° in II. The phenyl ring of the 4-amino­anti­py...

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Detalles Bibliográficos
Autores principales: Shankar, M. G., Kumaravel, R., Subashini, A., Ramamurthi, K., Kučeráková, Monika, Dušek, Michal, Stoeckli-Evans, Helen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10242735/
https://www.ncbi.nlm.nih.gov/pubmed/37288464
http://dx.doi.org/10.1107/S2056989023004085