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Stereochemical Analysis of Trifluoroacetamide Derivatives Based on Through-Space(1)H–(19)F Spin–Spin Couplings
[Image: see text] In this study, the conformational properties of tertiary trifluoroacetamides in dibenzoazepine (1a and 1b) and benzodiazepine (2a and 2b) derivatives, which exist as equilibrated E- and Z-amide conformers in solution, were investigated by (1)H and (19)F NMR spectroscopy. In all cas...
Autores principales: | , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10242751/ https://www.ncbi.nlm.nih.gov/pubmed/37200001 http://dx.doi.org/10.1021/acs.joc.3c00311 |