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Conversion of Racemic Alkyl Aryl Sulfoxides into Pure Enantiomers Using a Recycle Photoreactor: Tandem Use of Chromatography on Chiral Support and Photoracemization on Solid Support

[Image: see text] Chiral sulfoxides are valuable in the fields of medicinal chemistry and organic synthesis. A recycle photoreactor utilizing the concept of deracemization, where a racemate is converted into a pure enantiomer, is developed and successfully applied in the syntheses of chiral alkyl ar...

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Detalles Bibliográficos
Autores principales: Tozawa, Kumi, Makino, Kosho, Tanaka, Yuki, Nakamura, Kayo, Inagaki, Akiko, Tabata, Hidetsugu, Oshitari, Tetsuta, Natsugari, Hideaki, Kuroda, Noritaka, Kanemaru, Kunio, Oda, Yuji, Takahashi, Hideyo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10242752/
https://www.ncbi.nlm.nih.gov/pubmed/37155937
http://dx.doi.org/10.1021/acs.joc.3c00265