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One-Pot, Telescoped Alkenylation of Amides via Stable Tetrahedral Intermediates as Lithium Enolate Precursors
[Image: see text] A mild and efficient telescoped procedure for the stereoselective alkenylation of simple, non-activated amides using LiCH(2)SiMe(3) and carbonyl compounds as surrogates of alkenyllithium reagents is reported. Our methodology relies on the formation of stable tetrahedral intermediat...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10243110/ https://www.ncbi.nlm.nih.gov/pubmed/37218660 http://dx.doi.org/10.1021/acs.orglett.3c01269 |