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Functionalisation of conjugated macrocycles with type I and II concealed antiaromaticity via cross-coupling reactions

Conjugated macrocycles can exhibit concealed antiaromaticity; that is, despite not being antiaromatic, under specific circumstances, they can display properties typically observed in antiaromatic molecules due to their formal macrocyclic 4n π-electron system. Paracyclophanetetraene (PCT) and its der...

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Detalles Bibliográficos
Autores principales: Bennett, Troy L. R., Marsh, Adam V., Turner, James M., Plasser, Felix, Heeney, Martin, Glöcklhofer, Florian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10243434/
https://www.ncbi.nlm.nih.gov/pubmed/37288099
http://dx.doi.org/10.1039/d3me00045a