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Iron(ii) carboxylates and simple carboxamides: an inexpensive and modular catalyst system for the synthesis of PLLA and PLLA-PCL block copolymers

The combination of inexpensive Fe(ii) acetate with low molecular weight aliphatic carboxamides in situ generates an effective catalyst system for the ring opening polymerisation of lactones. PLLAs were produced in melt conditions with molar masses of up to 15 kg mol(−1), narrow dispersity (Đ = 1.03)...

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Detalles Bibliográficos
Autores principales: Kirchhecker, Sarah, Nguyen, Ngoc, Reichert, Stefan, Lützow, Karola, Eselem Bungu, Paul S., Jacobi von Wangelin, Axel, Sandl, Sebastian, Neffe, Axel T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10244980/
https://www.ncbi.nlm.nih.gov/pubmed/37293470
http://dx.doi.org/10.1039/d3ra03112h