Site-selective radical reactions of kinetically stable open-shell singlet diradicaloid difluorenoheteroles with tributyltin hydride and azo-based radical initiators

We have demonstrated site-selective radical reactions of the kinetically stable open-shell singlet diradicaloids difluoreno[3,4-b:4′,3′-d]thiophene (DFTh) and difluoreno[3,4-b:4′,3′-d]furan (DFFu) with tributyltin hydride (HSn(n-Bu)(3)) and azo-based radical initiators. Treatment of these diradicalo...

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Detalles Bibliográficos
Autores principales: Tabata, Naoki, Uchino, Takumi, Kitamura, Chitoshi, Yoshizawa, Kazunari, Shiota, Yoshihito, Kato, Shin-ichiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10246680/
https://www.ncbi.nlm.nih.gov/pubmed/37293653
http://dx.doi.org/10.1039/d3sc00381g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10246680/
https://www.ncbi.nlm.nih.gov/pubmed/37293653
http://dx.doi.org/10.1039/d3sc00381g

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