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Site-selective radical reactions of kinetically stable open-shell singlet diradicaloid difluorenoheteroles with tributyltin hydride and azo-based radical initiators
We have demonstrated site-selective radical reactions of the kinetically stable open-shell singlet diradicaloids difluoreno[3,4-b:4′,3′-d]thiophene (DFTh) and difluoreno[3,4-b:4′,3′-d]furan (DFFu) with tributyltin hydride (HSn(n-Bu)(3)) and azo-based radical initiators. Treatment of these diradicalo...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10246680/ https://www.ncbi.nlm.nih.gov/pubmed/37293653 http://dx.doi.org/10.1039/d3sc00381g |