Photoredox radical/polar crossover enables C–H gem-difunctionalization of 1,3-benzodioxoles for the synthesis of monofluorocyclohexenes

A photocatalytic C–H gem-difunctionalization of 1,3-benzodioxoles with two different alkenes for the synthesis of highly functionalized monofluorocyclohexenes is described. Using 4CzIPN as the photocatalyst, the direct single electron oxidation of 1,3-benzodioxoles allows their defluorinative coupli...

Descripción completa

Detalles Bibliográficos
Autores principales: Tian, Jiabao, Zhou, Lei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10246682/
https://www.ncbi.nlm.nih.gov/pubmed/37293655
http://dx.doi.org/10.1039/d3sc00912b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10246682/
https://www.ncbi.nlm.nih.gov/pubmed/37293655
http://dx.doi.org/10.1039/d3sc00912b

Ejemplares similares